Assembly and use of a geometrically compact powder layer

ABSTRACT

The invention relates to an additive production method involving the production of a layer of geometrically compact particles, having the following steps: a) providing a particle layer depositing arrangement, comprising a first and a second semi-chamber, wherein a partition separates the first semi-chamber from the second semi-chamber, and the partition is permeable for a dispersion medium and impermeable for particles dispersed in the dispersion medium; b) providing a particle dispersion comprising the dispersion medium and particles dispersed therein in the first semi-chamber, the particle dispersion being distributed substantially homogenously in the first semi-chamber; c) generating a pressure gradient between the first and the second semi-chamber such that the pressure gradient in the first semi-chamber causes a particle dispersion flow directed towards the partition; and d) depositing a particle aggregate material comprising geometrically compact particles on the partition by transporting a dispersion agent into the second semi-chamber.

The invention lies in the field of additive manufacturing, in particularthe manufacturing of prototypes of ceramic green bodies and relates tothe production of a highly dense powder bed and its use for themanufacturing of a solid.

In additive manufacturing methods which are based on the layer-by-layerstructure of the starting material as powder, the layer application isan essential process step. As a result of the repeated application ofpowder layers and the writing of the layer information into therespective layer, a component which is animated in the computer anddecomposed into virtual layers is constructed layer by layer fromsuccessive powder layers. The complete powder structure constructed byrepeated application of layers which includes the component is calledpowder bed.

The loose powder bulk materials of ceramic particles, metallic andpolymer powders which are constructed layer by layer in correspondingpowder-based additive manufacturing processes typically have only a lowdensity which on average corresponds to the bulk density of theparticles. This makes it difficult to generate a compact component inthe additive manufacturing process itself or during a subsequentsintering process. In the case of ceramic powders it is even impossibleto obtain a compact component starting from loose bulk materials.Furthermore, the low density of the powder bed brings about a lowstrength of the powder bed. Therefore a support structure for thecomponent must usually be constructed synchronously with the actualcomponent. The task of the support structure is the fixing of thecomponent with respect to the building platform and therefore in thecoordinate system of the installation. The construction of this supportstructure is time-consuming. Likewise the subsequent removal of thesupport structure from the actual component after completion of theconstruction process is time-consuming and typically cannot beautomated.

Against this background, an additive manufacturing method for producinga layer according to claim 1, the use of this method according to claim10, an additive manufacturing method for producing a solid according toclaim 11 and the use of such to produce a ceramic green body accordingto claim 20 are proposed.

Further embodiments, modifications and improvements are obtained byreference to the following description and the appended claims.

According to a first embodiment, an additive manufacturing method forproducing a layer of geometrically dense-packed particles is proposed.The additive method comprises the steps:

a) Providing a particle layer deposition arrangement. The particle layerdeposition arrangement has a first and a second half-space. Both have awall in common which as a dividing wall separates the first half-spacefrom the second half-space. The dividing wall is permeable for adispersion medium and impermeable for particles dispersed in thedispersion medium;b) Providing a particle dispersion in the first half-space wherein theparticle dispersion comprises the dispersion medium and particlesdispersed therein. The particle dispersion is distributed substantiallyhomogeneously in the first half-space, in particular it is distributedhomogeneously over the first half-space;c) Producing a pressure gradient between the first and the secondhalf-space so that the pressure gradient in the first half-space causesa flow of the particle dispersion directed towards the dividing wall. Inparticular the flow always brings new particles towards the dividingwall;d) Depositing a particle heap comprising geometrically dense-packedparticles on the dividing wall by transport of dispersion medium intothe second half-space. As a result of the filter action of the dividingwall and the continuous removal of particle-free dispersion mediumthrough the dividing wall, the particles are deposited before thedividing wall.

Advantages of this embodiment are obtained from a maximum packingdensity of the particle layer produced on the dividing wall which can beachieved for the given particle size and particle size distribution. Forexample, for a geometrically dense packing of spheres of the same spherediameter, a maximum packing density (spatial filling) is 74% assumingthat only complete particles are involved in forming the layer. Theactual density is then obtained from the average density of theparticles.

According to a further embodiment, the proposed additive manufacturingmethod further comprises the step e): smoothing the particle heap bymeans of scraping and/or grinding so that the particles of the particleheap are removed until the layer of geometrically dense-packed particleson the dividing wall has a uniform layer thickness.

Advantageously a constant layer thickness over the entire extension ofthe layer can thus be achieved.

According to a further development, a further step cc) is insertedbetween steps c) and d). This step cc) comprises providing a fluidizedbed of dispersed particles in the first half-space. In this case, thefluidized bed is in contact with the dividing wall at least partially.In addition, the particle dispersion of the fluidized bed has a higherdensity than in a section of the particle dispersion in the firsthalf-space located outside the fluidized bed.

Advantages of this embodiment comprise the advantages of fluidized bedsin general. The particles in the fluidized bed are mechanicallyactivated, any unevennesses of a surface over which the fluidized bed ispoured are rapidly compensated. As a result of this, the fluidized bedis an ideal source for the replenishment of particles from the particledispersion to the dividing surface i.e. to particles which have alreadyaccumulated there or which are fixed under the influence of the pressuregradient.

According to a further embodiment, the particle heap merely comprisestwo phases and comprises a particle phase and a fluid phase.

In particular the presence of only one fluid phase distinguishes theordered particle heap in the form of the layer of geometricallydense-packed particles from known particle layerings. For example, asubstantially dry particle dispersion present only in a gaseousdispersion medium can form the layer of geometrically densely-packedparticles. A layer of geometrically dense-packed particles which wasproduced with the aid of a liquid, for example, water and a gas, forexample air, has water and air adjacent to one another in its porespace. In this case, the water is present not only as a layer ofadsorptively bound water molecules: a layer of adsorptively bound watercovers almost all surfaces under normal conditions of anon-apparatus-controlled climate at sea level. In contrast to thisadsorptively bound water, for example when producing a particle heapfrom an aqueous suspension (slurry), the water is present as a regularlyliquid phase, for example, in particle intermediate spaces. For example,the layer of geometrically dense-packed particles produced according tothe method differs from a simple filter cake such as accumulates duringmechanical filtration on a filter by the lack of this water phase. Thisis particularly important when the layer of geometrically dense-packedparticles produced is to be thermally consolidated, for example. Ifliquid water is present in the layer, the layer would be loosened byescaping water vapour and lose its high packing density before theintended consolidation.

According to a further embodiment, the proposed additive manufacturingmethod further comprises a step designated as step f): placing the layerof geometrically dense-packed particles having uniform layer thicknessoutside the particle layer deposition arrangement.

Advantages of this embodiment are obtained from the time-delayed use ofthe layers produced. As a result of several runs, comprising steps a) tof), a plurality of different layers having uniform layer thicknesscomprising geometrically dense-packed particles can thus be provided.The layers can differ with regard to their layer thicknesses, but alsowith regard to the material character or the fine structure of theparticles forming the layers. Layers of different thickness cantherefore be stacked one upon the other. Likewise, layers can be stackedlaterally offset to one another. This affords extended possibilities formanufacturing three-dimensional objects.

According to a further embodiment, the provision of the particledispersion is accomplished by producing the dispersion directly in thefirst half-space. For example, a flow of the dispersion medium into aparticle storage container in the first half-space is introduced inorder to produce the particle dispersion. To this end, a directed jet ofthe dispersion medium can be introduced into the storage containerfilled with particles. Likewise, one or more baffle surfaces can be usedin order to achieve a homogeneous distribution of the particledispersion in the first half-space.

Advantages of this embodiment are obtained from the complete reusabilityof the particles provided. After a process run, remaining particles canbe collected again without losses and optionally formed into layers ofuniform, i.e. substantially constant, thickness in another method on adifferent type of dividing wall.

According to a further development of this embodiment, the production ofthe dispersion in the first half-space comprises the introduction of agas or a gas mixture into the first half-space.

Advantages of this embodiment are obtained from the flexibility of thedispersion method. The alignment, flow intensity (flux), flow profileetc. of the introduced gas flow can comprise a gas, various gases, orone or more gas mixtures. For example, the parameters of theintroduction can be adapted to a density of the particle material.

According to a further embodiment it is proposed to perform thesmoothing with the aid of a spreading unit where the spreading unitcomprises a rotating roller, a rotating brush, a blade and/or a slider.The rotating roller, the rotating brush, the blade and/or the slider areguided over the heap with the aid of the spreading unit so that theuniform layer thickness is achieved. In particular, the spreading unitcan be guided at a fixedly adjustable distance from the dividing wall ata constant speed of advance over the heap on the dividing wall. Auniform layer thickness which can be adjusted here lies in a range from500 nm to 5mm, in particular between 1 μm and 500 μm, preferably between30 μm and 200 μm.

Advantages of this embodiment consist, for example, in the possibilityof being able to adapt the spreading unit to the type of particle andparticle size.

According to a further embodiment, the blade and/or the slider are/isconnected rotatingly or rigidly to the spreading unit.

Advantages of this embodiment are obtained from the possibility of thegentle removal of existing unevennesses without the particle packingpresent under a removed portion of the layer becoming loosened.

According to a further embodiment, the use of a layer of geometricallydense-packed particles having uniform layer thickness in an additivemanufacturing method is proposed. This additive manufacturing methodcomprises the steps: g) stacking various layers of geometricallydense-packed particles having uniform layer thickness; gg) locallylimited linking of neighbouring particles of one layer over the entirethickness of this one layer; and ggg) at least partial fastening ofimmediately neighbouring layers of a layer stack to one another. In thiscase, the at least partial fastening is accomplished in regions oflocally limitedly linked neighbouring particles of the neighbouringlayers.

Advantages of this embodiment comprise the stacking of layers whichdiffer at least with regard to one parameter: layer thickness, size ofthe particles, chemical composition of the particles, in particular thepresence of functional groups on the surface of the particles.

According to a further development of the additive manufacturing methodfor producing a solid from layers of respectively uniform layerthickness comprising geometrically dense-packed particles, themanufacturing method comprises the steps:

i) providing a first layer of geometrically dense-packed particleshaving uniform layer thickness;ii) producing a layer stack by stacking a second layer of geometricallydense-packed particles on a surface of the first layer to produce alayer stack; or producing a layer stack by producing a second layer ofgeometrically dense-packed particles on a surface of the first layerusing a fluidized bed as particle source and an air or gas flow throughthe dividing wall and the already deposited layer located on thisdividing wall;iii) locally limited fixing of neighbouring particles, which extendsover the total layer thickness of the second layer and covers thesurface of the first layer, wherein the locally limited fixingcomprises:

a local application of a fixing agent or

a local exposure with respect to an electromagnetic radiation or

a local heating with a laser beam.

Advantages of this embodiment comprise the possibility of seriallyarranging a plurality of layers on one another one above the otherwhereby the layer produced previously on the dividing wall serves as ansupport for the subsequently additively deposited particle layer. Inparticular, this can be accomplished by a step-wise (taking place witheach completed layer deposition process) lowering of the dividing wall.

According to a further development of this embodiment, here designatedas step iv), the flux, i.e. the volume flow of the dispersion mediumthrough the dividing wall is kept constant at least during the additiveconstruction of a layer sequence or the production of the high-densitypowder bed. This means that a volume of the dispersion medium whichflows within a unit time from the first half-space through the dividingwall into the second half-space is substantially constant at leastduring the production of the layer stack according to step ii) withinthe limits of accuracy of the equipment used in the process technology(comprising, e.g. flow meter and/or flux meter and/or pressure sensorand/or pump etc.). This can be achieved in particular by the specificregulation of the pressure in the first half-space and/or in the secondhalf-space. For example, at least one pressure sensor can be disposed inthe second half-space, i.e. that space kept substantially free ofparticles by the dividing wall. Alternatively or additionally a flowmeter can be suitably arranged. Likewise, a flow measurement can be madeon, in or behind the dividing wall in the second half-space, forexample, by means of laser or ultrasound Doppler methods.

Advantages of this embodiment are obtained from a homogeneous packingdensity of the high-density powder bed, or over the height of the layerstack located on the dividing wall and growing with each additionalapplied layer. Similarly to this, the mean pore volume in the solidproduced is substantially identical. This is advantageous for the use ofthe solid as a prototype. Prototypes are frequently used not only tovisualize an external appearance but also for process optimization orare used for determining function-determining parameters. Against thisbackground, inhomogeneities in the solid are undesirable.

According to a further embodiment it is proposed that the layerthicknesses of at least two of the stacked particle layers differ.

Advantages of this embodiment consist in the large multiplicity ofthree-dimensional bodies which can be obtained.

According to a further embodiment, the stacking is accomplished by meansof: h) repeating steps b), c), d) and e) according to claim 1, whereinafter the smoothing according to step e) and before a repeateddeposition according to step d), a further step hh) is carried out. Thisstep hh) comprises a locally limited fixing of the smoothed layer ofdense-packed particles having uniform layer thickness. In this case, thelocally limited fixing is accomplished by a local application of afixing agent. Alternatively a local exposure to an electromagneticradiation, in particular to laser radiation, can also be accomplished.Typically the laser radiation effects a local heating of the particlelayer.

Advantages of this embodiment consist in the multiplicity of possiblecompaction principles: by sintering, by sectional fusing, by adhesion,by polymerizing, by forming covalent or non-covalent chemical bonds.

According to a further embodiment, the locally limited fixing isaccomplished exclusively on sections of the particle layer whichcorrespond to a contour of the layer-by-layer constructed solid or whichare directly adjacent to a contour and/or a surface section of thelayer-by-layer constructed solid.

Advantages of this embodiment are obtained from the acceleration of thework steps.

According to a further embodiment, it is proposed that in the method foradditive manufacturing of a solid in question here, the solid is a greenbody and the particles are a ceramic powder.

Advantages of this embodiment are obtained from the major practicalimportance of ceramic green bodies and the efficient manufacturingthereof.

According to a further development, the ceramic powder comprises powdershaving an average particle diameter of 50 nm to 500 μm, in particularparticles having average particle diameters between 200 nm and 250 μm,preferably between 1 μm and 100 μm.

According to a further embodiment, the additive method further comprisesreleasing the ceramic green body by means of removing non-fixedparticles or non-fixed fractions of the stacked layers. For example,loosely adhering particles on compacted or fixed fractions in the powderbed are removed until the actual green body is present and the removedloosely adhering particles are collected and can be supplied again to alayer deposition process.

Advantages of this embodiment are obtained from the recovery of thenon-fixed fractions. Largely closed manufacturing cycles can be achievedwhere starting materials (particles) are guided in a closed cycle.

According to a further embodiment, the release takes place automaticallywith the aid of an applied fluid, directed at a fluid pressure.

Advantages of this embodiment are obtained from the fact that the fluidused as dispersion medium can also be used for release.

According to a further embodiment, the release comprises an action or acoupling-in of acoustic and/or mechanical vibrations onto or into thelayer stack.

Advantages of this embodiment are again obtained from the possibilityfor automation. Said vibrations can be coupled-in without contact sothat there is no risk of contaminating or mechanically damaging thesurface of the green body.

Use of an additive manufacturing method according to one of thepreviously described methods to generate a ceramic green body.

The advantages of this embodiment primarily come into their own in theautomated prototype manufacturing/rapid prototyping and serialmanufacturing for batch sizes <1000: low material costs due to effectiveuse of high-quality and exactly classified particle fractions. The useof very small particles to construct particle layers by means ofconventional methods is limited by the inadequate pourability and thegrowing influence of surface charges on the pouring behaviour. Typicallyceramic particles below 30 μm are not sufficiently pourable for anefficient layer structure if they are applied by means of conventionalapplication techniques.

The embodiments described can be arbitrarily combined with one another.

In powder-based additive manufacturing methods, the layer application isaccomplished by coating a powder reservoir by means of a flat spreadingunit. This spreading unit can comprise a rotating roller or a blade or avibrating blade or similar. The actual process of application of thelayer is accomplished whereby the spreading unit has a fixed distancefrom the surface of the powder bed. This distance is uniform over theentire layer.

During application the powder can thus pour between the layer unit andthe powder bed and there form the respective layer. The pouring issubstantially gravity-driven. That is, the individual powder particlesfollow gravity. This has the result that depending on the orientation ofthe plane in which the spreading unit moves, an orientation of thepowder bed surface is accomplished with the surface normal of the powderbed surface in the direction of the gravitational force and an anglebetween the surface normal of the powder bed surface and the vector ofthe gravitational force is 0° (if horizontal layers are produced) orencloses an angle of less than 90° (if the layer application isaccomplished in an inclined plane). Typically this angle is less than60° since otherwise the stability of the powder bed would not beensured. The coating of the powder bed with a constant distance of thespreading unit from the powder bed surface ultimately defines thethickness of the applied powder layer.

The method described for application of powder layers is only possiblewith the aid of the gravitational force or a comparable force (e.g.centrifugal force). The powder particles are always in direct contactwith other powder particles, the powder reservoir. This results in arestricted mobility of the individual powder particles. This in turnhinders an optimal accumulation of powder particles to form a closestpacking on the surface of the powder bed. In suspension-based layerapplication methods a significantly higher packing density (>60%) isachieved. Such layer application methods are usual, for example, in theprocessing of ceramic particles in so-called slip casting. The liquidphase in this case acts almost as a lubricant between the individualpowder particles and promotes the formation of a dense packing.

One class of the early methods for additive manufacturing is formed bythe powder-based methods in which powder layers having a typicalthickness of 50 to 200 μm are stacked. In each of these layers thepowder particles are linked to one another and to the layer locatedunderneath in each case by a locally applied binder or by means of localfusion with the aid of a laser beam.

Binder-based powder methods were developed at Massachusetts Institute ofTechnology in Cambridge, USA, at the beginning of the nineties,laser-based methods were developed at the University of Texas in Austin,USA at the end of the eighties of the last century. They are designatedas 3D printing [1] or selective laser sintering [2]. Both methods havenow found a fixed place among the now numerous additive manufacturingmethods and certainly belong to the leading methods with regard to thenumber of fabricated components.

In addition to a continuous optimization of the technologies forming thebasis of these two methods, in the thirty years since their invention nosignificant further development has taken place in 3D printing or inselective laser sintering.

There are numerous methods in which a powdery material is used asstarting material. The three most commonly used methods are mentioned asan example:

Selective laser sintering (SLS) was originally developed for powder fromnylon polycarbonate and waxes and subsequently applied to metal powder.In a reactor powder layers are locally sintered onto a powder bed, wherethe sintering temperature is achieved by using lasers [2].

Selective laser melting (SLM) is a further development of selectivelaser sintering (SLS) and is used for powders which can be almostcompletely compacted by the formation of a melting phase, where themelting temperature is reached by using lasers.

Three-dimensional printing [1] uses polymer powders, metallic or ceramicpowder for application of layers which are then solidified by means oflocal injection of a binder. Technologies comparable to ink jet printingare used for injection of the binder.

All powder-based methods have the following common features:

1. The shaping is achieved not by removal of material but by addition ofmaterial. A local solidification of a powdery starting material takesplace.2. All the methods construct partial geometries comprising layers offinite thickness where all the layers are achieved by a so-called sliceprocess which is based directly on CAD data.3. The layer application is gravity-driven by means of a pourable powderwhich is formed into a layer by sliding a spreading unit over the powderbed.

The actual process of application of the layer is accomplished whereby aspreading unit has a fixed distance from the surface of the powder bedwhich is uniform over the entire layer and the powder pours betweenspreading unit and powder bed. Either the powder required for the layerstructure is delivered continuously by a metering unit when coating thepowder bed or a powder heap functions as a powder reservoir.

The pouring of the powder into the intermediate space between spreadingunit and powder bed is gravity-driven, i.e. the individual powderparticles follow gravity. This automatically brings about an orientationof the powder bed surface with the surface normal of the powder bedsurface in the direction of the gravitational force. An angle betweenthe surface normal of the powder bed surface and the gravitational forceis therefore 0° or encloses an angle of less than 90° preferably lessthan 60°. The coating of the powder bed with a constant distance of thespreading unit from the powder bed surface ultimately defines thethickness of the applied powder layer.

According to the present prior art, only pourable powders can be appliedto form layers having sufficient quality. This means that a certainminimum particle size of the powder must not be fallen below. In thecase of powders having too fine particles, the adhesive forces betweenthe particles are comparably as great as those forces which act on theparticles due to gravity. Typically ceramic particles of less than 30 μmare not sufficiently pourable for an efficient layer structure. Thiscounteracts a uniform pouring and therefore a uniform layer structure.Finer powders however afford numerous advantages, e.g. the possibilityof applying thinner layers. This results in a higher constructionaccuracy and a better subsequent compaction of components by sinteringsince smaller particles are more sinterable. The suction of fluidizedparticles through the powder bed now allows the use of finer particlesfor the construction of powder layers during additive manufacturing.Particles having a mean particle diameter of less than 30 μm, inparticular particles having a mean particle diameter between 200 nm and30 μm, preferably between 1 μm and 10 μm can thus be processed withoutany problems.

Starting from this, it is one aim to increase the density of the powderbed which is constructed by layer-by-layer application of loose powderin the powder-based manufacturing process and which encloses thecomponent to be constructed. One technical object therefore consists inproducing a compact powder bulk material (powder bed) during applicationof layers of a loose powder in the additive manufacturing process withloose powders.

Preferably according to all the embodiments described here, densestparticle packings are achieved which have a reduced pore volume comparedwith known loose dry powder bulk material. In particular, an achievedporosity of the particle heap achieved—optionally by means of negativepressure or by means of positive pressure—is less than 45%. For example,a fraction of the pore volume of the total volume of the particle heapproduced is a maximum of 43%. Accordingly, the density of the particleheap produced is at least 55% of the theoretical density of the ceramicpowder mixture used, or 57%. Here theoretical density is understood asthat density of a non-porous solid which is exhibited by the materialcomposition of the ceramic powder material which forms the heap at thedividing wall between first and second half-space. The porosity isdetermined gravimetrically with a precision of ±2% or pycnometricallywith a precision of less than or equal to ±0.1%. Advantageously 55%theoretical density or even 45% porosity is sufficient for a sinterableceramic green body. Thus, the method described for producing a layer ofa dry ceramic powder combined with a step comprising locally limitedfixing of neighbouring particles is suitable for producing a denselysinterable green body. For rigid, largely uniformly spherical particlesthere are numerous possibilities for a packing in the powder bed.Compared to the idealized densest packing of spheres, that packing whichhas a minimum pore space (<40 volume percent) or the highest attainabledensity (˜74% of the theoretical density) is considered to be thedensest packing.

A high density of the powder in the powder bed results in an improvedfusion or sintering behaviour during the compaction of the powder toform a compact component directly during the additive manufacturingprocess or in a subsequent sintering process.

By producing a gas flow directed in the direction of a flat filter,individual particles can be sucked onto the filter. The flat filter iscovered with a particle layer in this case. For this purpose powderparticles must be continuously supplied in the gas flow which can beachieved, for example, by the fluidization or atomization of powders bya second gas flow through a powder reservoir. Such an activated powderis also designated as fluidized bed. After a layer having a certainthickness has been deposited on the filter, no further particles aresupplied to the filter unit. The layer formed on the filter willpossibly not have a uniform layer thickness. A uniform layer thicknessis achieved in this case by an additional step of powder removal bymeans of a mechanical scraping or grinding.

A spreading unit which comprises substantially rigid or vibrating bladesor rotating rollers is used for this purpose.

When the layer is constructed, the layer information is transferred intothe layer as in the commonly used additive manufacturing methods bymeans of injection of a binder (3D printing) or by local laser sintering(selective sintering) etc. The process step of powder application isthen repeated where the powder layers already produced now also functionas filter. This process is repeated until all the layers of thecomponent to be constructed have been processed.

The packing density of the layer produced which is achieved with thismethod is comparable to the packing density of the layers in ceramicslip casting. The porosity of the layer produced is therefore less than40%.

By producing a gas flow through a flat filter which for example can bethe powder bed itself, individual powder particles can be sucked ontothe filter. Since the powder particles do not interfere with each otherduring the aspiration process until they have reached the poroussubstrate through which the gas flow is constructed, the particles canbe arranged largely freely and unhindered to form a densest packing.

Preferred places for a newly extracted particle on an already existingparticle layer are points at which a plurality of particles are incontact. At these points the gas flow due to the open porosity of thealready extracted powder is the strongest. Advantageously these areprecisely those points at which a new particle layer is to beaccumulated in the sense of a densest packing of spheres. Consequentlythe gas flow guides the individual particles to accumulation points onthe surface of a powder bed which correspond to a densest packing ofspheres in the case of almost spherical particles of the same size.

This is only possible as long as the particles to be accumulated do notinterfere with each other. For this reason the powder is supplied to thefilter in dispersed form. In the case of a dry powder and air asdispersion medium, an air flow prevents the powder particles from comingtoo close and interfering in their movement, this process is also calledair-activated powder. Furthermore, powder particles are suppliedcontinuously in the gas flow which is achieved, for example, by thefluidization or atomization of powders by a second gas flow which runsthrough a powder reservoir. Such an activated powder is also designatedas fluidized bed.

Previous processes for the layer application of loose powders inadditive manufacturing processes do not take into account the fact thatthe individual powder particles require time and a certain free space toaccumulate to form a densest packing. In all known methods for the layerapplication of loose powder layers in additive manufacturing, powderbulk material impedes this free movement of powder particles. The purelygravitational forces during layer application of pourable powders arenot sufficient to guide the particles to the optimal positions for adensest packing of spheres. The combination of a second air flow guidedthrough the powder bed, the powder thus fluidized or powder dust aspowder source with the first air flow guided through the filter and usedfor layer construction make this possible. The use of air flows toproduce a (powder) fluidized bed as powder source is described as anexample hereinbefore. However the person skilled in the art is awarethat other gases or gas mixtures can also be used as air for producingthe powder fluidized bed. Likewise, fluids other than air, gases or gasmixtures, for example, liquids can also be used as dispersion media toproduce the powder fluidized bed (powder source).

According to previously known methods, no extraction of particles from aparticle dust or another type of fluidized powder with the aid of an airflow through the powder bed is used to apply powder layers inpowder-based additive manufacturing methods. The previously describednew method allows a higher packing density of the particles in theapplied powder layer.

Furthermore, there is no longer the problem that very fine particles inthe dry state have a low flowability and therefore are no longersuitable for layer application below a certain mean particle diameter.However, fine particles specifically afford the advantage of a highsurface quality, i.e. a low roughness of the prototypes produced, theadvantage of an improved sinterability of the green bodies produced oradvantages when adjusting specific particularly fine-crystallinestructures, e.g. for a ceramic component.

An increased density of the powder bed results in a firmer powder bedwhereby the support function of the powder bed is increased.Advantageously the respectively desired bodies can thus be formed in thepowder bed without additional support structures.

Furthermore, layer application is possible in almost any arbitraryorientation of the layer since the forces which act on the powderparticles through the gas flow exceed the gravitational force.

In summary, an additive manufacturing method is proposed comprising theproduction of at least one layer of geometrically densely packedparticles, which is used to produce a shaped body and which comprisesthe following steps:

a) providing a particle layer deposition arrangement comprising a firstand a second half-space, where a dividing wall separates the firsthalf-space from the second half-space and the dividing wall is permeablefor a dispersion medium and impermeable for particles dispersed in thedispersion medium;b) providing a particle dispersion comprising the dispersion medium andparticles dispersed therein in the first half-space, wherein theparticle dispersion is distributed substantially homogeneously in thefirst half-space;c) producing a pressure gradient between the first and the secondhalf-space so that the pressure gradient in the first half-space bringsabout a flow of the particle dispersion directed towards the dividingwall;d) depositing a particle heap comprising geometrically densely packedparticles on the dividing wall by transport of dispersion medium intothe second half-space.Preferably the particles are homogeneously distributed in the form of afluidized bed formed in the first half-space and are arranged from thefluidized bed on the dividing wall in geometrically dense packing. Inthis way, additional layers can be additively constructed on the layerthus produced. This is accomplished, for example, by moving the dividingwall in the direction of the second half-space. Alternatively additionallayers thus produced or produced differently can be stacked on theadditively produced layer on a side of the dividing wall facing thefirst half-space. The densely packed particles of the layers arrangedone above the other in the form of a layer stack are each fixed locally,i.e. in discrete sections of the respective layer. These discretesections typically correspond to a contour, an inner or an outer surfaceof a shaped body present after completion of the process embedded in thecompacted powder bed. During fixing the fixed particles of the upperlayer are bound to the fixed particles of the layer located thereunder.The shaped body can be released by re-suspension or re-dispersion ofnon-fixed fractions of particles.

Although specific embodiments have been presented and described herein,it lies within the framework of the present invention to suitably modifythe embodiments shown without departing from the scope of protection ofthe present invention. The following claims form a first non-bindingattempt to generally define the invention.

REFERENCES

[1] Sachs E. M., Haggerty J. S., Cima M. J., Williams P. A., Inventors;Massachusetts Institute of Technology, Assignee. Three-dimensionalprinting techniques. U.S. Pat. No. 5,204,055; 1993 Apr. 20;

[2] Deckard C. R., Inventor; Board of Regents, The University of TexasSystem, Assignee. Method and apparatus for producing parts by selectivesintering. U.S. Pat. No. 4,863,538; 1989 Sep. 5

What is claimed is:
 1. Additive manufacturing method for producing alayer of geometrically densely packed particles, comprising: a)providing a particle layer depositing arrangement comprising a first anda second half-space, where a dividing wall separates the firsthalf-space from the second half-space and the dividing wall is permeablefor a dispersion medium and impermeable for particles dispersed in thedispersion medium; b) providing a particle dispersion comprising thedispersion medium and particles dispersed therein in the firsthalf-space, wherein the particle dispersion is distributed substantiallyhomogeneously in the first half-space; c) producing a pressure gradientbetween the first and the second half-space so that the pressuregradient in the first half-space brings about a flow of the particledispersion directed towards the dividing wall; d) depositing a particleheap comprising geometrically densely packed particles on the dividingwall by transport of dispersion medium into the second half-space,wherein providing the particle dispersion is accomplished by producingthe particle dispersion directly in the first half-space.
 2. Theadditive manufacturing method according to claim 1, further comprising:e) smoothing the particle heap by means of scraping and/or grinding sothat the particles of the particle heap are removed until the layer ofgeometrically densely packed particles on the dividing wall has auniform layer thickness.
 3. The additive manufacturing method accordingto claim 1, wherein a step is further inserted between step c) and stepd): cc) providing a fluidized bed of dispersed particles in the firsthalf-space, wherein the fluidized bed is in contact with the dividingwall at least in sections and a density of the dispersion of dispersedparticles in the fluidized bed is higher than in a remaining volume ofthe first half-space.
 4. The additive manufacturing method according toclaim 1, wherein the particle heap merely comprises two phases,comprising a particle phase and a fluid phase.
 5. The additivemanufacturing method according to claim 1, further comprising: f)placing the layer of geometrically densely packed particles havinguniform layer thickness outside the particle layer depositionarrangement.
 6. (canceled)
 7. The additive manufacturing methodaccording to claim 5, wherein producing comprises the introduction of agas or a gas mixture.
 8. The additive manufacturing method according toclaim 1, wherein smoothing is accomplished with the aid of a spreadingunit and the spreading unit comprises a rotating roller, a rotatingbrush, a blade and/or a slider, wherein the rotating roller, therotating brush, the blade and/or the slider is guided over the heap withthe aid of the spreading unit so that the uniform layer thickness isachieved, wherein the uniform layer thickness can be adjusted in a rangefrom 500 nm to 5 mm, in particular between 1 μm and 500 μm, preferablybetween 30 μm and 200 μm.
 9. The additive manufacturing method accordingto claim 8, wherein the blade and/or the slider are/is connectedrotatingly or rigidly to the spreading unit.
 10. Use of a layer ofgeometrically densely packed particles having uniform layer thickness inan additive manufacturing method comprising: g) stacking various layersof geometrically dense-packed particles having uniform layer thickness;gg) locally limited linking of neighbouring particles of one layer overthe entire thickness of this one layer; and ggg) at least partialfastening of immediately neighbouring layers of a layer stack to oneanother, wherein the at least partial fastening is accomplished inregions of locally limitedly linked neighbouring particles of theneighbouring layers.
 11. Additive manufacturing method for producing asolid from layers of respectively uniform layer thickness comprisinggeometrically densely packed particles, wherein the manufacturing methodcomprises: i) providing a first layer of geometrically dense-packedparticles having uniform layer thickness; ii) producing a layer stack bystacking a second layer of geometrically dense-packed particles on asurface of the first layer to produce a layer stack; or producing alayer stack by producing a second layer of geometrically dense-packedparticles on a surface of the first layer using a fluidized bed asparticle source and an air or gas flow through the dividing wall and thealready deposited layer located on this dividing wall; iii) locallylimited fixing of neighbouring particles, which extends over the totallayer thickness of the second layer and covers the surface of the firstlayer, wherein the locally limited fixing comprises: a local applicationof a fixing agent or a local exposure with respect to an electromagneticradiation or a local heating with a laser beam.
 12. The additivemanufacturing method according to claim 11 further comprising: iv)regulating a volume flow of the dispersion medium so that a volume ofthe dispersion medium which flows through the dividing wall within aunit time is constant at least during the production of the layer stackaccording to step ii).
 13. The additive manufacturing method accordingto claim 11, wherein the layer thicknesses of at least two of thestacked particle layers differ from one another.
 14. The additivemanufacturing method according to claim 11, wherein the stacking isaccomplished by means of: h) repeating steps b), c), d) and e) accordingto claim 1, wherein after the smoothing according to step e) and beforea repeated deposition according to step d), a further step hh) iscarried out: hh) locally limited fixing of the smoothed layer ofdense-packed particles having uniform layer thickness, wherein thelocally limited fixing is accomplished by a local application of afixing agent, by a local exposure to an electromagnetic radiation, inparticular by a laser-induced local heating.
 15. The additivemanufacturing method according to claim 11, wherein the local limitedfixing is accomplished exclusively on sections of the particle layerwhich correspond to a contour of the layer-by-layer constructed solid orwhich are directly adjacent to a contour and/or a surface section of thelayer-by-layer constructed solid.
 16. The additive manufacturing methodaccording to claim 11, wherein the solid is a green body and theparticles are a ceramic powder.
 17. The additive manufacturing methodaccording to claim 16, wherein the ceramic powder comprises powdershaving an average particle diameter of 50 nm to 500 μm, in particularparticles having average particle diameters between 200 nm and 250 μm,preferably between 1μm and 100 μm.
 18. The additive manufacturing methodaccording to claim 16, further comprising: releasing the ceramic greenbody by means of removing a non-fixed fraction of the stacked layers.19. The additive manufacturing method according to claim 18, wherein therelease takes place automatically with the aid of an applied fluid,directed with a fluid pressure.
 20. The additive manufacturing methodaccording to claim 19, wherein the release further comprises an actionof acoustic and/or mechanical vibrations on the layer stack.
 21. Use ofan additive manufacturing method according to claim 11 to generate aceramic green body.